My best advice is to put the woman first (most of the time). You want to get a woman warmed up in the bedroom because it will take her longer to get revved up and ready. Start slow with light touching in non-sexual areas, such as her hands, arms, shoulders, and legs. As she gets more warmed up to you she will move her energy into you. As you notice this you can start kissing her. As the kissing intensifies, so will the petting. Then you can move to the more sexual areas and into positions to have sex with her.
Once you engage in sex then you'll want to work on making her orgasm first. This will reward you in the long run, especially if you can get her to orgasm multiple times before you do.